cis-Diaquabis[(E)-4-(2-hydroxybenzylideneamino)benzoato-kappa2O,O']cadmium(II): two-dimensional layers built from strong O-H...O hydrogen bonding in the coordination sphere

Acta Crystallogr C. 2006 May;62(Pt 5):m183-5. doi: 10.1107/S0108270106009723. Epub 2006 Apr 13.

Abstract

In the title compound, [Cd(C14H10NO3)2(H2O)2], which crystallizes with Z = 4 in the space group C2c, the Cd atom is located on a twofold rotation axis and coordinated by six O atoms from two water molecules and two carboxylate groups of two planar 4-(2-hydroxybenzylideneamino)benzoate ligands, with a dihedral angle of 85.6 (1) degrees between them. Strong O-H...O hydrogen bonding in the coordination sphere, together with pi-pi stacking interactions, assemble the molecules into two-dimensional layers.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Benzylidene Compounds / chemistry*
  • Cadmium / chemistry*
  • Crystallography, X-Ray
  • Hydrogen Bonding
  • Organometallic Compounds / chemistry*

Substances

  • Benzylidene Compounds
  • Organometallic Compounds
  • Cadmium