trans-Dichlorotetrabenzimidazolecadmium(II) tetrabenzimidazole: a three-dimensional supramolecular structure built from C-H...pi, N-H...Cl and N-H...N hydrogen bonds

Acta Crystallogr C. 2006 May;62(Pt 5):m180-2. doi: 10.1107/S0108270106008973. Epub 2006 Apr 13.

Abstract

The title compound, [CdCl2(C7H6N2)4].4C7H6N2, consists of a Cd(Bzim)4Cl2 complex (Bzim is benzimidazole) lying on a fourfold rotation axis in the space group P4nc, and four benzimidazole molecules which are linked to the coordinated benzimidazole unit by N-H...N hydrogen bonds. One N-H...Cl and three C-H...pi hydrogen bonds link these units into a three-dimensional supramolecular structure.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Benzimidazoles / chemistry*
  • Cadmium / chemistry*
  • Crystallography, X-Ray
  • Hydrogen Bonding
  • Organometallic Compounds / chemistry*

Substances

  • Benzimidazoles
  • Organometallic Compounds
  • Cadmium