Synthesis and structure of the bilayer hydrate Na0.3NiO2.1.3D2O

Sangmoon Park; Yongjae Lee; Margaret Elcombe; Thomas Vogt

doi:10.1021/ic060235x

Synthesis and structure of the bilayer hydrate Na0.3NiO2.1.3D2O

Inorg Chem. 2006 May 1;45(9):3490-2. doi: 10.1021/ic060235x.

Authors

Sangmoon Park¹, Yongjae Lee, Margaret Elcombe, Thomas Vogt

Affiliation

¹ USC NanoCenter and Department of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina 29208, USA.

PMID: 16634577
DOI: 10.1021/ic060235x

Abstract

The metal oxide bilayer deuterate (hydrate) Na(0.3)NiO2.1.3D2O (Na(0.3)NiO2.1.3H2O) were prepared from NaxNiO2 by extracting Na+ cations and simultaneously intercalating fully and nondeuterated water. High-resolution neutron powder diffraction, thermogravimetric analysis, and inductively coupled plasma atomic emission spectroscopy were used to show that a Na(0.3)(D2O)(1.3) network separates layers of edge-sharing NiO6 octahedra.