Synthesis and characterization of aluminum-containing tin(IV) heterobimetallic sulfides

Zhi Yang; Xiaoli Ma; Vojtech Jancik; Zhensheng Zhang; Herbert W Roesky; Jörg Magull; Mathias Noltemeyer; Hans-Georg Schmidt; Raymundo Cea-Olivares; Rubén A Toscano

doi:10.1021/ic052139m

Synthesis and characterization of aluminum-containing tin(IV) heterobimetallic sulfides

Inorg Chem. 2006 Apr 17;45(8):3312-5. doi: 10.1021/ic052139m.

Authors

Zhi Yang¹, Xiaoli Ma, Vojtech Jancik, Zhensheng Zhang, Herbert W Roesky, Jörg Magull, Mathias Noltemeyer, Hans-Georg Schmidt, Raymundo Cea-Olivares, Rubén A Toscano

Affiliation

¹ Institut für Anorganische Chemie der Georg-August-Universität Göttingen, Tammannstrasse 4, D-37077 Göttingen, Germany.

PMID: 16602790
DOI: 10.1021/ic052139m

Abstract

Three novel aluminum-containing tin(IV) heterobimetallic sulfides are reported. The reaction of [LAl(SLi)2(THF)2]2 (1) [L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3] with Ph2SnCl2, Me2SnCl2, and SnCl4 in THF respectively afforded LAl(mu-S)2SnPh2 (2), LAl(mu-S)2SnMe2 (3), and LAl(mu-S)2Sn(mu-S)2AlL (4) in moderate yields. Compounds 2, 3, and 4 were characterized by elemental analysis, NMR, electron-impact mass spectrometry, and single-crystal X-ray structural analysis.