Immobilization of sodium ions on the pore surface of a porous coordination polymer

Satoshi Horike; Ryotaro Matsuda; Daisuke Tanaka; Motohiro Mizuno; Kazunaka Endo; Susumu Kitagawa

doi:10.1021/ja0606879

Immobilization of sodium ions on the pore surface of a porous coordination polymer

J Am Chem Soc. 2006 Apr 5;128(13):4222-3. doi: 10.1021/ja0606879.

Authors

Satoshi Horike¹, Ryotaro Matsuda, Daisuke Tanaka, Motohiro Mizuno, Kazunaka Endo, Susumu Kitagawa

Affiliation

¹ Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Japan.

PMID: 16568985
DOI: 10.1021/ja0606879

Abstract

A porous coordination polymer (PCP) with immobilization of sodium cations on the pore surface has been synthesized, by employing a bifunctional carboxylate/sulfonate ligand, and structurally characterized. The porous framework with 1D channels of the dimension of 4.9 x 4.9 A2 shows high thermal stability ( approximately 330 degrees C), affording Type I adsorption isotherms for CO2, acetone, and benzene. The chemical shift of 13C NMR and characteristic adsorption energy (betaE0) of acetone adsorbed in this compound represent the Lewis acidity of this framework.