Thiocarbonyl compounds as regulating reagent in the radical addition of tertiary amines with alkenes using photoelectron transfer conditions

Dominique Harakat; Jens Pesch; Sinisa Marinković; Norbert Hoffmann

doi:10.1039/b600220j

Thiocarbonyl compounds as regulating reagent in the radical addition of tertiary amines with alkenes using photoelectron transfer conditions

Org Biomol Chem. 2006 Apr 7;4(7):1202-5. doi: 10.1039/b600220j. Epub 2006 Feb 14.

Authors

Dominique Harakat¹, Jens Pesch, Sinisa Marinković, Norbert Hoffmann

Affiliation

¹ Laboratoire des Réactions Sélectives et Applications, UMR CNRS et Université de Reims Champagne-Ardenne, UFR Sciences, B.P. 1039, F-51687 Reims, cedex 02, France.

PMID: 16557304
DOI: 10.1039/b600220j

Abstract

The efficiency of the photoinduced radical addition of tertiary amines to olefinic double bonds is significantly enhanced and the stereoselectivity is influenced when thiocarbonyl compounds are added to the reaction mixture.