Abstract
A novel approach to the synthesis of urea glycosides in aqueous media has been explored. Steyermark's glucopyranosyl oxazolidinone was found to be a good synthon for anchoring glucosyl moieties onto amines and thiols. The present method was successfully applied to establish a new route for the synthesis of urea-tethered neoglycoconjugates and pseudooligosaccharides in water.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Amines / chemistry
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Carbohydrate Sequence
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Glycoconjugates / chemical synthesis*
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Glycosides / chemical synthesis
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Glycosides / chemistry
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Molecular Sequence Data
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Oligosaccharides / chemical synthesis*
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Oxazolidinones / chemistry
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Sulfhydryl Compounds / chemistry
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Urea / analogs & derivatives
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Urea / chemical synthesis
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Urea / chemistry*
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Water / chemistry
Substances
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Amines
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Glycoconjugates
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Glycosides
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Oligosaccharides
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Oxazolidinones
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Sulfhydryl Compounds
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Water
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Urea