Bromoiodinanes with an I(III)-Br bond: preparation, X-ray crystallography and reactivity as electrophilic brominating agents

D Christopher Braddock; Gemma Cansell; Stephen A Hermitage; Andrew J P White

doi:10.1039/b600455e

Bromoiodinanes with an I(III)-Br bond: preparation, X-ray crystallography and reactivity as electrophilic brominating agents

Chem Commun (Camb). 2006 Apr 7:(13):1442-4. doi: 10.1039/b600455e. Epub 2006 Feb 22.

Authors

D Christopher Braddock¹, Gemma Cansell, Stephen A Hermitage, Andrew J P White

Affiliation

¹ Department of Chemistry, Imperial College London, London, UKSW7 2AZ. c.braddock@imperial.ac.uk

PMID: 16550294
DOI: 10.1039/b600455e

Abstract

Bromoiodinanes--conveniently and directly prepared from iodobenzenecarbinols and N-bromosuccinimide, and characterised for the first time crystallographically--act as electrophilic bromine donors.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Bromides / chemistry*
Bromine / chemistry*
Crystallography, X-Ray
Electrons*
Iodine / chemistry*
Models, Molecular
Molecular Structure

Substances

Bromides
Iodine
Bromine