Photocatalytic activity of R3MO7 and R2Ti2O7 (R=Y, Gd, La; M=Nb, Ta) for water splitting into H2 and O2

Ryu Abe; Masanobu Higashi; Kazuhiro Sayama; Yoshimoto Abe; Hideki Sugihara

doi:10.1021/jp0552933

Photocatalytic activity of R3MO7 and R2Ti2O7 (R=Y, Gd, La; M=Nb, Ta) for water splitting into H2 and O2

J Phys Chem B. 2006 Feb 9;110(5):2219-26. doi: 10.1021/jp0552933.

Authors

Ryu Abe¹, Masanobu Higashi, Kazuhiro Sayama, Yoshimoto Abe, Hideki Sugihara

Affiliation

¹ National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan. ryu-abe@cat.hokudai.ac.jp

PMID: 16471807
DOI: 10.1021/jp0552933

Abstract

The photocatalytic activities of R3MO7 and R2Ti2O7 (R=Y, Gd, La; M=Nb, Ta) strongly depended on the crystal structure. Overall, photocatalytic water splitting into H2 and O2 proceeded over La3TaO7 and La3NbO7, which have an orthorhombic weberite structure, Y2Ti2O7 and Gd2Ti2O7, which have a cubic pyrochlore structure, and La2Ti2O7, which has a monoclinic perovskite structure. All of these materials are composed of a network of corner-shared octahedral units of metal cations (TaO6, NbO6, or TiO6); materials without such a network were inactive. The octahedral network certainly increased the mobility of electrons and holes, thereby enhancing photocatalytic activity.