A new radical-based route to calothrixin B

M-Lluïsa Bennasar; Tomàs Roca; Francesc Ferrando

doi:10.1021/ol052600e

A new radical-based route to calothrixin B

Org Lett. 2006 Feb 16;8(4):561-4. doi: 10.1021/ol052600e.

Authors

M-Lluïsa Bennasar¹, Tomàs Roca, Francesc Ferrando

Affiliation

¹ Laboratory of Organic Chemistry, Faculty of Pharmacy, University of Barcelona, Barcelona 08028, Spain.

PMID: 16468711
DOI: 10.1021/ol052600e

Abstract

[structure: see text] A high-yielding totally regioselective intramolecular homolytic acylation of a quinoline ring constitutes the key step in a new synthesis of the pentacyclic indolo[3,2-j]phenanthridine alkaloid calothrixin B.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Cyanobacteria / chemistry
Cyclization
Indole Alkaloids / chemical synthesis*
Indole Alkaloids / chemistry
Molecular Structure

Substances

Indole Alkaloids
calothrixin B