Abstract
A novel heteroditopic calix[4]diquinone receptor capable of binding an anion and cation simultaneously in a cooperative fashion is shown only to recognise halide anions in the presence of a suitable cobound cationic guest species, and displays affinity for certain ion-pairs where no affinity for either of the free ions is observed.
Publication types
-
Research Support, Non-U.S. Gov't
MeSH terms
-
Acetonitriles / chemistry
-
Anions / chemistry
-
Binding Sites
-
Calixarenes / chemistry*
-
Calixarenes / metabolism
-
Cations / chemistry
-
Chlorides / chemistry
-
Heterocyclic Compounds / chemistry*
-
Heterocyclic Compounds / metabolism
-
Ionophores / chemistry*
-
Ionophores / metabolism
-
Kinetics
-
Magnetic Resonance Spectroscopy
-
Models, Chemical
-
Models, Molecular
-
Protons
-
Quinones / chemistry*
-
Quinones / metabolism
Substances
-
Acetonitriles
-
Anions
-
Cations
-
Chlorides
-
Heterocyclic Compounds
-
Ionophores
-
Protons
-
Quinones
-
Calixarenes