Polarization relaxation induced by a depolarization field in ultrathin ferroelectric capacitors

Phys Rev Lett. 2005 Dec 2;95(23):237602. doi: 10.1103/PhysRevLett.95.237602. Epub 2005 Dec 1.

Abstract

Time-dependent polarization relaxation behavior induced by a depolarization field E(d) was investigated on high-quality ultrathin SrRuO3/BaTiO3/SrRuO3 capacitors. The E(d) values were determined experimentally from an applied external field to stop the net polarization relaxation. These values agree with those from the electrostatic calculations, demonstrating that a large E(d) inside the ultrathin ferroelectric layer could cause severe polarization relaxation. For numerous ferroelectric devices of capacitor configuration, this effect will set a stricter size limit than the critical thickness issue.