A steep one-step [HS-HS] to [LS-LS] spin transition in a 4,4'-bipyridine linked one-dimensional coordination polymer constructed from a pyrazolato bridged Fe(II) dimer

Ko Yoneda; Keiichi Adachi; Shinya Hayami; Yonezo Maeda; Motomi Katada; Akira Fuyuhiro; Satoshi Kawata; Sumio Kaizaki

doi:10.1039/b512266j

A steep one-step [HS-HS] to [LS-LS] spin transition in a 4,4'-bipyridine linked one-dimensional coordination polymer constructed from a pyrazolato bridged Fe(II) dimer

Chem Commun (Camb). 2006 Jan 7:(1):45-7. doi: 10.1039/b512266j. Epub 2005 Oct 20.

Authors

Ko Yoneda¹, Keiichi Adachi, Shinya Hayami, Yonezo Maeda, Motomi Katada, Akira Fuyuhiro, Satoshi Kawata, Sumio Kaizaki

Affiliation

¹ Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka, 560-0043, Japan.

PMID: 16353087
DOI: 10.1039/b512266j

Abstract

The variable temperature magnetic susceptibility, X-ray crystallography, and Mössbauer and Raman spectra of a new dinuclear complex-based one-dimensional coordination polymer [[Fe(II)2(NCS)2(mu-bpypz)2](micro-4,4'-bpy)].MeOH demonstrated a steep one-step [HS-HS] to [LS-LS] spin transition.