Synthesis of hydrophosphorylated fullerene under neutral conditions

Hiroyuki Isobe; Ai-Jan Chen; Niclas Solin; Eiichi Nakamura

doi:10.1021/ol0522586

Synthesis of hydrophosphorylated fullerene under neutral conditions

Org Lett. 2005 Dec 8;7(25):5633-5. doi: 10.1021/ol0522586.

Authors

Hiroyuki Isobe¹, Ai-Jan Chen, Niclas Solin, Eiichi Nakamura

Affiliation

¹ Department of Chemistry and ERATO (JST), The University of Tokyo, Hongo, Tokyo 113-0033, Japan. hsobe@chem.s.u-tokyo.ac.jp

PMID: 16321009
DOI: 10.1021/ol0522586

Abstract

[chemical reaction: see text]. A variety of phosphorous compounds such as secondary phosphines, phosphine oxides, phosphinates, and phosphonates undergo addition to [60]fullerene in DMSO/C6H5Cl without extraneous reagents to produce hydrophosphorylated fullerene derivatives in moderate to high yield.