Stereospecific addition of H-P bond to alkenes: a simple method for the preparation of (R(P))-phenylphosphinates

Li-Biao Han; Chang-Qiu Zhao

doi:10.1021/jo051582b

Stereospecific addition of H-P bond to alkenes: a simple method for the preparation of (R(P))-phenylphosphinates

J Org Chem. 2005 Nov 25;70(24):10121-3. doi: 10.1021/jo051582b.

Authors

Li-Biao Han¹, Chang-Qiu Zhao

Affiliation

¹ National Institute of Advanced Industrial Science and Technology, Tsukuba, Ibaraki 305-8565, Japan. libiao-han@aist.go.jp

PMID: 16292852
DOI: 10.1021/jo051582b

Abstract

[reaction: see text] A variety of functionalized optically pure (R(P))-alkylphenylphosphinates are readily prepared by stereospecific radical or base-catalyzed additions of the easily available (R(P))-menthyl phenylphosphinate to alkenes.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Alkenes / chemical synthesis*
Alkenes / chemistry
Catalysis
Molecular Structure
Phosphinic Acids / chemistry*
Stereoisomerism

Substances

Alkenes
Phosphinic Acids
phenylphosphinic acid