Cyanide-bridged W(V)-Mn(II) bimetallic double-zigzag chains with a metamagnetic nature

Jung Hee Yoon; Hyoung Chan Kim; Chang Seop Hong

doi:10.1021/ic051415u

Cyanide-bridged W(V)-Mn(II) bimetallic double-zigzag chains with a metamagnetic nature

Inorg Chem. 2005 Oct 31;44(22):7714-6. doi: 10.1021/ic051415u.

Authors

Jung Hee Yoon¹, Hyoung Chan Kim, Chang Seop Hong

Affiliation

¹ Department of Chemistry, Korea University, Seoul.

PMID: 16241120
DOI: 10.1021/ic051415u

Abstract

A cyanide-bridged W-Mn bimetallic compound [W(CN)(6)(bpy)](2)[Mn(H(2)O)(2)].4H(2)O (1) (bpy = 2,2'-bipyridine) with a one-dimensional, crossed double-zigzag chain structure was prepared by self-assembling [W(CN)(6)(bpy)](-) and Mn(2+) ions in a 2:1 reaction ratio. The magnetic properties of 1 exhibit a field-induced metamagnetic behavior.