Abstract
The structure and physicochemistry of the [Ni(II)(AAZ)(2)](ClO(4))(2) (1) complex (AAZ = 6-amino-6-methylperhydro-1,4-diazepine), as a system that is able to mimic some important chelate properties of 1,4,7-triazacyclononane, are reported. The syntheses of a new unsymmetric AAZ-functionalized ligand and the structure of its first heterodinuclear Fe(III)Zn(II) complex are also presented.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Azepines / chemistry*
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Crystallography, X-Ray
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Heterocyclic Compounds / chemistry*
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Ligands
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Models, Molecular
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Molecular Mimicry
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Molecular Structure
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Nickel / chemistry*
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Organometallic Compounds / chemical synthesis
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Organometallic Compounds / chemistry*
Substances
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6-amino-6-methylperhydro-1,4-diazepine
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Azepines
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Heterocyclic Compounds
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Ligands
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Organometallic Compounds
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1,4,7-triazacyclononane
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Nickel