Hydrogen bonding and pi-pi interactions in a laminar structure: benzene-1,3-dicarboxylic acid-4-methylpyridine (1/2)

Acta Crystallogr C. 2005 Oct;61(Pt 10):o593-5. doi: 10.1107/S0108270105026181. Epub 2005 Sep 10.

Abstract

The title complex, C8H6O4.2C6H7N, consists of two crystallographically independent 1:2 clusters of benzene-1,3-dicarboxylic acid and 4-methylpyridine. Each cluster, the components of which are linked by O-H...N hydrogen bonds, is almost planar by alignment of C-H...O hydrogen bonds. Herring-bone ribbons of clusters are formed by other C-H...O hydrogen bonds, and these ribbons are further packed to form a laminar structure by pi-pi interactions.

MeSH terms

  • Crystallography, X-Ray
  • Hydrogen Bonding
  • Models, Molecular
  • Molecular Conformation
  • Phthalic Acids / chemistry*
  • Picolines / chemistry*

Substances

  • Phthalic Acids
  • Picolines
  • isophthalate
  • 4-methylpyridine