Synthesis of alpha-D-idoseptanosyl glycosides using an S-phenyl septanoside donor

Org Lett. 2005 Oct 13;7(21):4709-12. doi: 10.1021/ol051912e.

Abstract

[reaction: see text] An S-phenyl alpha-D-idoseptanoside donor was used in the selective preparation of a series of alpha-D-idoseptanosyl glycosides. Glycosylation of a methyl beta-D-glycero-D-guloseptanoside acceptor with the new donor constituted the first synthesis of a septanose disaccharide.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Carbohydrate Conformation
  • Disaccharides / chemical synthesis*
  • Disaccharides / chemistry
  • Glycosylation
  • Molecular Structure
  • Stereoisomerism
  • Thioglycosides / chemistry*

Substances

  • Disaccharides
  • Thioglycosides