Hydrogen-bonded self-assemblies in a polychlorotriphenylmethyl radical derivative substituted with six meta-carboxylic acid groups

Chem Commun (Camb). 2005 Oct 14:(38):4801-3. doi: 10.1039/b508952b. Epub 2005 Aug 26.

Abstract

The synthesis, self assembly and magnetic properties of a polychlorotriphenylmethyl radical, substituted with six meta-carboxylic groups, are reported showing that radical-radical hydrogen bonds in the solid state yield to very weak intermolecular ferromagnetic interactions.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Carboxylic Acids / chemistry*
  • Crystallography, X-Ray
  • Free Radicals / chemical synthesis
  • Free Radicals / chemistry
  • Hydrocarbons, Aromatic / chemical synthesis*
  • Hydrocarbons, Aromatic / chemistry*
  • Hydrogen Bonding
  • Magnetics
  • Models, Molecular
  • Molecular Structure
  • Polymers / chemical synthesis*
  • Polymers / chemistry*
  • Temperature

Substances

  • Carboxylic Acids
  • Free Radicals
  • Hydrocarbons, Aromatic
  • Polymers