Complete 1H and 13C NMR assignments of aurasperone A and fonsecinone A, two bis-naphthopyrones produced by Aspergillus aculeatus

Magn Reson Chem. 2005 Nov;43(11):962-5. doi: 10.1002/mrc.1654.

Abstract

Complete assignments of 1H and 13C NMR chemical shifts of the polyketides aurasperone A and fonsecinone A were made by means of nuclear Overhauser enhancement and heteronuclear NMR correlation experiments. These compounds were isolated for the first time from Aspergillus aculeatus, an endophytic fungus obtained from leaves of Melia azedarach(Meliaceae).

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aspergillus / chemistry*
  • Carbon Isotopes
  • Chromones / chemistry*
  • Chromones / isolation & purification
  • Magnetic Resonance Spectroscopy / methods*
  • Magnetic Resonance Spectroscopy / standards*
  • Molecular Structure
  • Naphthalenes / chemistry*
  • Naphthalenes / isolation & purification
  • Protons
  • Pyrones / chemistry*
  • Pyrones / isolation & purification
  • Reference Standards

Substances

  • Carbon Isotopes
  • Chromones
  • Naphthalenes
  • Protons
  • Pyrones
  • fonsecinone A
  • aurasperone A