Spectroscopy and upconversion of Dy3+ doped in sodium zinc phosphate glass

Spectrochim Acta A Mol Biomol Spectrosc. 2005 Dec;62(4-5):1120-4. doi: 10.1016/j.saa.2005.03.028. Epub 2005 Sep 8.

Abstract

Optical absorption and fluorescence spectra of Dy3+ doped in sodium zinc phosphate glasses have been reported. Judd-Ofelt theory has been applied to analyze the spectra and determine the optical parameters such as transition probabilities, radiative lifetime, stimulated emission cross-section, etc. The fluorescence intensity of Dy3+ corresponding to 4F9/2-->6H13/2 transition increases with increasing concentration of Dy3+ but at higher concentrations, concentration quenching is observed. The radiative lifetime of the 4F9/2 level at 1 mol% concentration of Dy3+ in this host is found to be 541 micros. Emission corresponding to 4F9/2-->6H13/2 transition (570 nm) is observed on excitation with NIR radiation due to upconversion. An attempt is made to explain this observation.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Dysprosium / chemistry*
  • Energy Transfer
  • Glass / chemistry*
  • Luminescence
  • Models, Chemical
  • Phosphates / chemistry*
  • Sodium / chemistry*
  • Spectrometry, Fluorescence
  • Zinc Compounds / chemistry*

Substances

  • Phosphates
  • Zinc Compounds
  • Dysprosium
  • zinc phosphate
  • Sodium