Dynamic helicity inversion in an octahedral cobalt(II) complex system via solvato-diastereomerism

Hiroyuki Miyake; Hideki Sugimoto; Hitoshi Tamiaki; Hiroshi Tsukube

doi:10.1039/b506130j

Dynamic helicity inversion in an octahedral cobalt(II) complex system via solvato-diastereomerism

Chem Commun (Camb). 2005 Sep 14:(34):4291-3. doi: 10.1039/b506130j. Epub 2005 Aug 2.

Authors

Hiroyuki Miyake¹, Hideki Sugimoto, Hitoshi Tamiaki, Hiroshi Tsukube

Affiliation

¹ Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan. miyake@sci.osaka-cu.ac.jp

PMID: 16113725
DOI: 10.1039/b506130j

Abstract

The helical sense of a mononuclear Co(II) complex with an amino acid-based chiral tetradentate ligand was dynamically inverted by changing the solvent component.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Amino Acids / chemistry
Circular Dichroism
Hydrogen-Ion Concentration*
Ligands
Magnetic Resonance Spectroscopy
Molecular Conformation
Organometallic Compounds / chemistry
Solvents
Stereoisomerism

Substances

Amino Acids
Ligands
Organometallic Compounds
Solvents
bis(acrylonitrile)(2,5,8,11-tetraaza-4,5,8,9-tetramethyldodecane)cobalt(II)
nitrato(2,5,8,11-tetraaza-4,5,8,9-tetramethyldodecane)cobalt(II)