Synthesis and structure of the bidimensional zeolite ITQ-32 with small and large pores

Angel Cantín; Avelino Corma; Sandra Leiva; Fernando Rey; Jordi Rius; Susana Valencia

doi:10.1021/ja053040h

Synthesis and structure of the bidimensional zeolite ITQ-32 with small and large pores

J Am Chem Soc. 2005 Aug 24;127(33):11560-1. doi: 10.1021/ja053040h.

Authors

Angel Cantín¹, Avelino Corma, Sandra Leiva, Fernando Rey, Jordi Rius, Susana Valencia

Affiliation

¹ Instituto de Tecnología Química (UPV-CSIC), Universidad Politécnica de Valencia, Avda. de los Naranjos s/n, 46022 Valencia, Spain.

PMID: 16104706
DOI: 10.1021/ja053040h

Abstract

A new bidimensional zeolite containing 8R and 12R pores, denoted as ITQ-32, has been synthesized and its structure solved from powder X-ray diffraction data. This zeolite presents a relatively large pore volume (0.16 cm3/g) and pore apertures of 3.5 x 4.3 A and can be prepared as a nearly pure silica zeolite and as aluminosilicate. In the latest case, acidic properties are developed.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Crystallization
Crystallography, X-Ray
Models, Molecular
Porosity
Zeolites* / chemical synthesis
Zeolites* / chemistry

Substances

ITQ-32
Zeolites