Thermal radiation from C(N)+ and La@C(N)+

J Chem Phys. 2005 Jul 22;123(4):044310. doi: 10.1063/1.1925277.

Abstract

The radiative cooling of positively charged fullerene and endohedral fullerene fragments of C60, C70, C84, and La@C82 has been measured in a time-of-flight mass spectrometer. The radiative cooling is measured via its influence on the metastable decay. The emissivity extracted from the data is between 4x10(-4) and 13x10(-4). These values agree fairly well with the emissivity calculated from considering the low-energy tail of the surface plasmon. No major difference is found in the emission behavior of empty and endohedral fullerenes.