Observation of OD- by microwave spectroscopy

Gabriele Cazzoli; Cristina Puzzarini

doi:10.1063/1.1978870

Observation of OD- by microwave spectroscopy

J Chem Phys. 2005 Jul 22;123(4):041101. doi: 10.1063/1.1978870.

Authors

Gabriele Cazzoli¹, Cristina Puzzarini

Affiliation

¹ Dipartimento di Chimica G. Ciamician, Università di Bologna, Via Selmi 2, I-40126 Bologna, Italy. gabriele.cazzoli@unibo.it

PMID: 16095338
DOI: 10.1063/1.1978870

Abstract

For the first time the rotational spectrum of the molecular anion OD- has been observed by microwave spectroscopy. OD- has been produced both by a positive and negative glow discharge; by investigating the Doppler shift in both cases, the unshifted frequency of the J=1<--0 rotational transition has been derived. This allowed us to improve the value of the ground-state rotational constant: B(0)=299 264.940(90) MHz. In order to assess that a negative ion has really been observed, the cation N2H+ has been produced and investigated in the same experimental conditions.