Monitoring industrial wastewater by online GC-MS with direct aqueous injection

Anal Bioanal Chem. 2006 Mar;384(5):1113-22. doi: 10.1007/s00216-005-3366-2. Epub 2005 Jul 28.

Abstract

An online GC-MS-system for automated monitoring of crude wastewater at a complex chemical production site is presented. The modular system is, in principal, based on commercial equipment, but utilizes a special, two-stage injector, which consists of a splitless vaporization chamber on top of a PTV injector filled with Tenax. This set-up enables direct injection of wastewater. Almost 140 volatile and semi-volatile compounds are calibrated down to 1 mg L(-1), which is sufficient for analysis of the influent of the wastewater-treatment plant. Two instruments analyze alternately, every 20 min, and the instrument cycle time is 40 min. The quantitative results are transferred to a database which is connected to a process-control system. Depending on the nature and concentration of a compound, an alarm can be generated and the wastewater stream can be diverted into an "off spec tank" if necessary. The GC-MS-system operates quasi-continuously with a system availability >98%. Data quality is automatically controlled in each run and by daily analysis of a quality-control sample. The development of a novel stacked PTV-PTV injector design to expand the range of analytes to selected basic compounds is described.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Gas Chromatography-Mass Spectrometry / instrumentation*
  • Gas Chromatography-Mass Spectrometry / methods*
  • Industrial Waste / analysis*
  • Sensitivity and Specificity
  • Water / chemistry
  • Water Pollution, Chemical / analysis*

Substances

  • Industrial Waste
  • Water