New adsorbents were prepared and tested for the separation of propane-propylene mixtures by adsorption. The ordered mesoporous material SBA-15 was used as the starting material for silver-ion deposition for pi-complexation with propylene. Two different loadings of silver were evaluated. Adsorption equilibrium and kinetic measurements of propane and propylene in the matrix (pure SBA-15) and the silver-modified adsorbents were performed at 323, 343, and 373 K. In this temperature range, the selectivity of propylene in one of the materials (Ag/SBA-15 = 0.5) is in the range 13-22 because the amount of propane adsorbed is very small, 0.095 mmol/g of propane versus 1.12 mmol/g of propylene at 100 kPa and 343 K. The diffusivity of both hydrocarbons is not seriously affected by the introduction of silver into the mesoporous structure.