Variational bounds for the relaxation times of swelling gels

Phys Rev E Stat Nonlin Soft Matter Phys. 2005 Apr;71(4 Pt 1):041404. doi: 10.1103/PhysRevE.71.041404. Epub 2005 Apr 19.

Abstract

Variational bounds are found for the relaxation times of a gel of general shape swelling in a solvent based on the stress-diffusion coupling model. It is shown that in the case of free swelling, the longest relaxation time is inversely proportional to the osmotic modulus K in the limit of K-->0 and K-->infinity . This indicates that the relaxation time diverges at the point of K=0 . The divergence, however, disappears if a part of the gel is mechanically constrained.