Tuning the intermolecular dative interactions by altering the ligand planarity and counter cations in vanadyl(IV) complexes

Kwan Mook Kim; Dongwon Lee; Mi Sook Seo; Hyunjung Park; Rita Song; Moo-Jin Jun; Wonwoo Nam

doi:10.1039/b501350j

Tuning the intermolecular dative interactions by altering the ligand planarity and counter cations in vanadyl(IV) complexes

Dalton Trans. 2005 May 5:(9):1567-9. doi: 10.1039/b501350j. Epub 2005 Apr 7.

Authors

Kwan Mook Kim¹, Dongwon Lee, Mi Sook Seo, Hyunjung Park, Rita Song, Moo-Jin Jun, Wonwoo Nam

Affiliation

¹ Department of Chemistry, Division of Nano Sciences, and Center for Biomimetic Systems, Ewha Womans University, Seoul 120-750, Korea. kkmook@ewha.ac.kr

PMID: 15852103
DOI: 10.1039/b501350j

Abstract

A vanadyl(iv) complex, K2V(O)(dtoym)2, forms polymeric interactions via intermolecular dative bonds; the intermolecular dative interaction is tuned by changes of the ligand planarity and counter cations of the vanadyl complex.