A catalytic enantioselective hetero Diels-Alder approach to the C20-C32 segment of the phorboxazoles

Brian S Lucas; Laura M Luther; Steven D Burke

doi:10.1021/jo050034v

A catalytic enantioselective hetero Diels-Alder approach to the C20-C32 segment of the phorboxazoles

J Org Chem. 2005 Apr 29;70(9):3757-60. doi: 10.1021/jo050034v.

Authors

Brian S Lucas¹, Laura M Luther, Steven D Burke

Affiliation

¹ Department of Chemistry, University of Wisconsin, 1101 University Avenue, Madison, Wisconsin 53706-1396, USA.

PMID: 15845024
DOI: 10.1021/jo050034v

Abstract

[reaction: see text] An efficient synthesis of the C20-C32 segment of the phorboxazoles has been achieved using an enantioselective hetero Diels-Alder reaction catalyzed by Jacobsen's Cr(III) amino indanol Schiff base catalyst.

Publication types

Research Support, U.S. Gov't, P.H.S.

MeSH terms

Catalysis
Chromium / chemistry
Heterocyclic Compounds, 4 or More Rings / chemical synthesis*
Heterocyclic Compounds, 4 or More Rings / chemistry
Indicators and Reagents
Molecular Structure
Oxazoles / chemical synthesis*
Oxazoles / chemistry
Schiff Bases / chemistry

Substances

Heterocyclic Compounds, 4 or More Rings
Indicators and Reagents
Oxazoles
Schiff Bases
Chromium
phorboxazole A

Abstract

Publication types

MeSH terms

Substances

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