8-hydroxyquinoline complexes of Na(I), Ca(II), Mg(II), Zn(II), Cu(II), Mn(II), Al(III), In(III) and La(III) were synthesized. Photoluminescence (PL) and UV-Vis absorption spectra characteristics of these complexes and 8-hydroxyquinoline are reported. Except complexes of Cu and Mn, most of these complexes reveal photoluminescence. With the polarization force of metal cations increasing, the PL peak shows red-shift and two broad absorption peak in UV-Vis (300-400nm) absorption spectra distinctly appears apart.