The energies of CrKbeta X-Rays in metel Cr, Cr2Os and K2CrO4, which are excited respectively by gamma-ray 59.6keV from radioactive source 241Am, have been measured by Si(Li) spectrometry. It is shown in the experiment that the peak of CrKbeta X-ray in K2CrO4 shifts 2.12 +/- 0.27eV compared to that in metel Cr.