2-Phosphinophenolate complexes: formation and crystal structure of a novel trinuclear mu-O nickel(II)-tris(P(intersection)O-chelate)

Joachim Heinicke; Normen Peulecke; Konstantin Karaghiosoff; Peter Mayer

doi:10.1021/ic0484304

2-Phosphinophenolate complexes: formation and crystal structure of a novel trinuclear mu-O nickel(II)-tris(P(intersection)O-chelate)

Inorg Chem. 2005 Apr 4;44(7):2137-9. doi: 10.1021/ic0484304.

Authors

Joachim Heinicke¹, Normen Peulecke, Konstantin Karaghiosoff, Peter Mayer

Affiliation

¹ Institut für Chemie und Biochemie, Ernst-Moritz-Arndt-Universität Greifswald, D-17487 Greifswald, Germany. heinicke@uni-greifswald.de

PMID: 15792446
DOI: 10.1021/ic0484304

Abstract

A novel linear trinuclear mu-O-bridging 2-phosphinophenolate nickel(II) complex with fac-tris(P(intersection)O- chelates) in the terminal positions and the three oxygen atoms each facing the central nickel(II) cation was synthesized and structurally characterized by X-ray crystallography. To the best of our knowledge, this is the first example of an octahedral Ni(II) tris(P(intersection)O- chelate).