Abstract
The use of hypervalent iodine(III) reagents allowed us to develop the novel and efficient direct synthesis of N,O-acetal compounds via the oxidative fragmentation reaction of alpha-amino acids or alpha-amino alcohols; furthermore, we succeeded in developing an improved synthesis of the key intermediate of discorhabdins.
MeSH terms
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Acetals / chemistry*
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Amino Alcohols / chemistry
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Iodine Compounds / chemical synthesis*
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Iodine Compounds / chemistry
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Molecular Structure
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Nitrogen / chemistry*
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Oxidation-Reduction
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Oxygen / chemistry*
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Quinones / chemical synthesis
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Quinones / chemistry*
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Serine / analogs & derivatives
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Serine / chemistry
Substances
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Acetals
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Amino Alcohols
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Iodine Compounds
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Quinones
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Serine
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serine methyl ester
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Nitrogen
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Oxygen