Synthesis and crystal structure of a salen-type copper(II) complex derived from 3,5'-O-dimethyl-2',3'-diamino-2',3'-dideoxy-beta-D-xylo-uridine

Org Biomol Chem. 2005 Apr 7;3(7):1170-1. doi: 10.1039/b500785b. Epub 2005 Feb 22.

Abstract

We report the synthesis of the first 2',3'-diamino substituted uridine derivative with xylo-configuration, its use as starting material for the synthesis of salen-type ligands and the first structurally characterised copper(II) complex thereof.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Copper / chemistry*
  • Crystallography, X-Ray
  • Deoxy Sugars / chemical synthesis
  • Deoxy Sugars / chemistry*
  • Ethylenediamines / chemistry
  • Magnetic Resonance Spectroscopy
  • Models, Molecular
  • Organomercury Compounds / chemical synthesis
  • Organomercury Compounds / chemistry
  • Uridine / analogs & derivatives*
  • Uridine / chemical synthesis
  • Uridine / chemistry

Substances

  • Deoxy Sugars
  • Ethylenediamines
  • Organomercury Compounds
  • Copper
  • disalicylaldehyde ethylenediamine
  • Uridine