New oxorhenium(V) complexes with 2N2S donor sets and radiochemical behavior of their technetium analogs

Pulak K Dhara; Biswajit Das; Jem-Mau Lo; Pabitra Chattopadhyay

doi:10.1016/j.apradiso.2004.10.002

New oxorhenium(V) complexes with 2N2S donor sets and radiochemical behavior of their technetium analogs

Appl Radiat Isot. 2005 May;62(5):729-35. doi: 10.1016/j.apradiso.2004.10.002. Epub 2004 Nov 23.

Authors

Pulak K Dhara¹, Biswajit Das, Jem-Mau Lo, Pabitra Chattopadhyay

Affiliation

¹ Department of Chemistry, The University of Burdwan, Golapbag, Burdwan 713104, India.

PMID: 15763479
DOI: 10.1016/j.apradiso.2004.10.002

Abstract

Oxorhenium(V) complexes of two thioether amines have been synthesized and characterized spectroscopically. The five-coordinated ReO(3+) moiety is satisfied by the amine compounds behaving as dibasic tetradentate (NSSN) ligands and a chloride ion. The radioanalytical studies of their technetium analogs have been carried out at different pH values in the range 3-10. The solvent extraction, TLC, electrophoresis and HPLC studies using (99m)Tc radiotracer indicate that the labeled complex with the TcO(3+) core is similar to the rhenium complex with the ReO(3+) core.