A high spin molecular square based on square pyramidal Co(II) and tetrahedral Mn(II) centers: [{MnIICl2}2{CoII(triphos)(CN)2}2]

Ferdi Karadas; Eric J Schelter; Andrey V Prosvirin; John Bacsa; Kim R Dunbar

doi:10.1039/b415168b

A high spin molecular square based on square pyramidal Co(II) and tetrahedral Mn(II) centers: [{MnIICl2}2{CoII(triphos)(CN)2}2]

Chem Commun (Camb). 2005 Mar 21:(11):1414-6. doi: 10.1039/b415168b. Epub 2005 Feb 2.

Authors

Ferdi Karadas¹, Eric J Schelter, Andrey V Prosvirin, John Bacsa, Kim R Dunbar

Affiliation

¹ Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, TX 77842-3012, USA.

PMID: 15756321
DOI: 10.1039/b415168b

Abstract

A high spin molecular square of square pyramidal Co(II) and tetrahedral Mn(II) corners exhibiting an overall S= 4 ground state has been crystallized and its magnetic properties investigated.