Bis[2,2'-(phenylphosphinediyl)dibenzenethiolato-kappa3S,P,S']germanium(IV)

Acta Crystallogr C. 2005 Feb;61(Pt 2):m84-6. doi: 10.1107/S0108270104033256. Epub 2005 Jan 15.

Abstract

Two tridentate phosphinethiolate ligands, [PhP(C6H4S-2)2]2-, coordinate to the Ge(IV) centre in a facial manner yielding the title compound, [Ge(C18H13PS2)2], which exhibits a pseudo-twofold symmetry with the two P-atom donors in a cis configuration. The Ge centre has a distorted octahedral environment. Two phenyl rings, one from each of the phosphinethiolate ligands, are parallel to one another, indicating pi-pi interactions. The molecules are linked by weak C-H...pi and C-H...S interactions.