Hairpin rubber elasticity

Eur Phys J E Soft Matter. 2005 Jan;16(1):97-107. doi: 10.1140/epje/e2005-00012-3. Epub 2005 Jan 31.

Abstract

We model the elastic properties of main chain liquid crystalline elastomers, formed by cross linking chains in a strongly nematic state, when they have hairpin defects. We study the response of the elastomer to imposed uniaxial extension along the nematic direction, and employ a microscopic model of how the deformation is distributed non-affinely amongst the hairpin and straight chain populations. The rubber shows a plateau in the stress as a function of the elongation imposed along the director. It is a consequence of the depletion of the actively stretching population of hairpin chains and should not be confused with soft elasticity effects associated with director rotation.

MeSH terms

  • Computer Simulation
  • Elasticity
  • Elastomers / analysis
  • Elastomers / chemistry*
  • Models, Chemical*
  • Models, Molecular*
  • Models, Statistical
  • Molecular Conformation
  • Polymers / analysis
  • Polymers / chemistry
  • Stress, Mechanical

Substances

  • Elastomers
  • Polymers