Stereoselective synthesis of 2,5-disubstituted-1,4-oxathiane S-oxides

Org Biomol Chem. 2005 Feb 7;3(3):404-6. doi: 10.1039/b415529g. Epub 2004 Dec 21.

Abstract

Beta-allyloxy and beta-propargyloxy tert-butyl sulfoxides undergo tandem sulfoxide eliminination-intramolecular sulfenic acid addition reactions to produce 1,4-oxathiane S-oxides.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallography, X-Ray
  • Cyclization
  • Heterocyclic Compounds, 1-Ring / chemical synthesis*
  • Heterocyclic Compounds, 1-Ring / chemistry*
  • Models, Molecular
  • Molecular Conformation
  • Molecular Structure
  • Stereoisomerism
  • Sulfoxides / chemical synthesis*
  • Sulfoxides / chemistry*

Substances

  • Heterocyclic Compounds, 1-Ring
  • Sulfoxides