Neutral acetohydroxamic acid coordination to a mononuclear Ni(II) center stabilized by an intramolecular hydrogen-bonding interaction

Chem Commun (Camb). 2005 Jan 28:(4):489-91. doi: 10.1039/b413683g. Epub 2004 Dec 2.

Abstract

Treatment of a new chelate ligand having both amide- and phenyl-appended pyridyl moieties with Ni(ClO4).6H2O and acetohydroxamic acid in methanol solution results in the production of a novel pseudo-octahedral Ni(II) complex having a neutral acetohydroxamic acid ligand stabilized by a hydrogen-bonding interaction.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Crystallography, X-Ray
  • Hydrogen Bonding
  • Hydroxamic Acids / chemistry*
  • Models, Molecular
  • Molecular Structure
  • Nickel / chemistry*
  • Organometallic Compounds / chemistry*

Substances

  • Hydroxamic Acids
  • Organometallic Compounds
  • acetohydroxamic acid
  • Nickel