[Fe(sal2-trien)][Ni(dmit)2]: towards switchable spin crossover molecular conductors

Stéphane Dorbes; Lydie Valade; José A Real; Christophe Faulmann

doi:10.1039/b412182a

[Fe(sal2-trien)][Ni(dmit)2]: towards switchable spin crossover molecular conductors

Chem Commun (Camb). 2005 Jan 7:(1):69-71. doi: 10.1039/b412182a. Epub 2004 Nov 16.

Authors

Stéphane Dorbes¹, Lydie Valade, José A Real, Christophe Faulmann

Affiliation

¹ Centre National de la Recherche Scientifique, Laboratoire de Chimie de Coordination (LCC/CNRS/UPR8241), 205, route de Narbonne, 31077, Toulouse Cedex, France.

PMID: 15614375
DOI: 10.1039/b412182a

Abstract

A cooperative spin transition behaviour with a wide hysteresis loop (30 K) around 240 K has been observed, for the first time, in a salt based on the redox active [Ni(dmit)(2)](-), anion and the [Fe(sal(2)-trien)](+) spin crossover cation.