Stereochemistry of contiguous cyclopropane formation from cascade cyclization of a skipped dienyl homoallyl triflate

Christopher M Lincoln; James D White; Alexandre F T Yokochi

doi:10.1039/b412811g

Stereochemistry of contiguous cyclopropane formation from cascade cyclization of a skipped dienyl homoallyl triflate

Chem Commun (Camb). 2004 Dec 21:(24):2846-7. doi: 10.1039/b412811g. Epub 2004 Oct 28.

Authors

Christopher M Lincoln¹, James D White, Alexandre F T Yokochi

Affiliation

¹ Department of Chemistry, Oregon State University, Corvallis, Oregon 97331-4003, USA.

PMID: 15599436
DOI: 10.1039/b412811g

Abstract

Solvolysis of asymmetric homoallylic triflates bearing a terminal stannyl substituent gives disubstituted cyclopropanes and bicyclopropanes bearing differentiated termini in high enantiopurity.