Quinoline-2(1H)-thione, a structure with Z' = 8

Acta Crystallogr C. 2004 Dec;60(Pt 12):o865-7. doi: 10.1107/S0108270104025636. Epub 2004 Nov 11.

Abstract

The title compound, C(9)H(7)NS, crystallizes as the thione tautomer with Z' = 8 (four independent dimers with local inversion symmetry via two N-H...S=C hydrogen-bond systems). The dimers are arranged in chains parallel to [-110], each chain being crystallographically independent. These chains are associated into layers via stacking of ring systems. The Z' value can be rationalized in terms of a factor 2 for dimer formation without crystallographic symmetry and an additional factor 4 for differing stacking environments.