Abstract
Only two-fold amination occurs when 3 molar equivalents of TMPH are offered to a 1:1 BuNa-Bu2Mg mixture; adding TMEDA gives the mixed alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP)Mg(TMP)], which itself affords the phenyl-bridged analogue when reacted with benzene.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Amides / chemistry*
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Amination
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Crystallography, X-Ray
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Magnesium / chemistry*
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Models, Molecular
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Molecular Structure
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Organometallic Compounds / chemistry*
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Organometallic Compounds / isolation & purification*
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Sodium / chemistry*
Substances
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Amides
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Organometallic Compounds
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Sodium
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Magnesium