Filling of the mott-hubbard gap in the high temperature photoemission spectrum of (V0.972Cr0.028)2O3

Phys Rev Lett. 2004 Aug 13;93(7):076404. doi: 10.1103/PhysRevLett.93.076404. Epub 2004 Aug 12.

Abstract

Photoemission spectra of the paramagnetic insulating phase of (V0.972Cr0.028)2O3, taken in ultrahigh vacuum up to the unusually high temperature (T) of 800 K, reveal a property unique to the Mott-Hubbard (MH) insulator that has not been observed previously. With increasing T the MH gap is filled by spectral weight transfer, in qualitative agreement with high-T theoretical calculations combining dynamical mean field theory and band theory in the local density approximation.