Mononuclear nitrogen/sulfur-ligated cobalt(II) methoxide complexes: structural, EPR, paramagnetic 1H NMR, and electrochemical investigations

Dalton Trans. 2004 Aug 21:(16):2398-9. doi: 10.1039/B408177C. Epub 2004 Jul 20.

Abstract

The first examples of mononuclear nitrogen/sulfur-ligated Co(II) alkoxide complexes, species of relevance to a reactive intermediate observed for Co(II)-substituted liver alcohol dehydrogenase, have been isolated and characterized by multiple methods including X-ray crystallography, EPR, paramagnetic (1)H NMR, and cyclic voltammetry.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, U.S. Gov't, Non-P.H.S.
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Alcohol Dehydrogenase / chemistry
  • Cobalt / chemistry*
  • Crystallography, X-Ray
  • Electrochemistry
  • Electron Spin Resonance Spectroscopy
  • Liver / enzymology
  • Magnetic Resonance Spectroscopy
  • Models, Molecular
  • Nitrogen / chemistry*
  • Sulfur / chemistry*

Substances

  • Cobalt
  • Sulfur
  • Alcohol Dehydrogenase
  • Nitrogen