Abstract
The first examples of mononuclear nitrogen/sulfur-ligated Co(II) alkoxide complexes, species of relevance to a reactive intermediate observed for Co(II)-substituted liver alcohol dehydrogenase, have been isolated and characterized by multiple methods including X-ray crystallography, EPR, paramagnetic (1)H NMR, and cyclic voltammetry.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, U.S. Gov't, Non-P.H.S.
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Research Support, U.S. Gov't, P.H.S.
MeSH terms
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Alcohol Dehydrogenase / chemistry
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Cobalt / chemistry*
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Crystallography, X-Ray
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Electrochemistry
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Electron Spin Resonance Spectroscopy
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Liver / enzymology
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Magnetic Resonance Spectroscopy
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Models, Molecular
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Nitrogen / chemistry*
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Sulfur / chemistry*
Substances
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Cobalt
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Sulfur
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Alcohol Dehydrogenase
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Nitrogen