Structural characterization and luminescence behavior of a silver(I) 1D polymeric chain constructed via a Bridge with unusual 4,5-diazospirobifluorene and perchlorate

Chih-Chieh Wang; Cheng-Han Yang; Shih-Min Tseng; Sue-Yi Lin; Ti-Yu Wu; Ming-Ren Fuh; Gene-Hsiang Lee; Ken-Tsung Wong; Ruei-Tang Chen; Yi-Ming Cheng; Pi-Tai Chou

doi:10.1021/ic0351794

Structural characterization and luminescence behavior of a silver(I) 1D polymeric chain constructed via a Bridge with unusual 4,5-diazospirobifluorene and perchlorate

Inorg Chem. 2004 Aug 9;43(16):4781-3. doi: 10.1021/ic0351794.

Authors

Chih-Chieh Wang¹, Cheng-Han Yang, Shih-Min Tseng, Sue-Yi Lin, Ti-Yu Wu, Ming-Ren Fuh, Gene-Hsiang Lee, Ken-Tsung Wong, Ruei-Tang Chen, Yi-Ming Cheng, Pi-Tai Chou

Affiliation

¹ Department of Chemistry, Soochow University, Taipei, Taiwan 111, R.O.C. ccwang@mail.scu.edu.tw

PMID: 15285642
DOI: 10.1021/ic0351794

Abstract

A new polymeric silver complex, [Ag(2)(L(2))(ClO(4))(2)] (L = 4,5-diazospirobifluorene), has been synthesized and shown to exhibit interesting luminescence properties in a single crystal. Structural analysis reveals a one-dimensional chain, which contains a [Ag(2)(L(2))](2+) dimer bridged with ClO(4)(-). The Ag...Ag distances are 2.776(1) and 4.575(1) A incorporated by two L ligands and by a ClO(4)(-) bridge, respectively.