Unprecedented eight-palladium(I) crown-cycle with metal-metal unsupported bonds

Inma Angurell; Isabel Martínez-Ruiz; Oriol Rossell; Miquel Seco; Pilar Gómez-Sal; Avelino Martin

doi:10.1039/b405532b

Unprecedented eight-palladium(I) crown-cycle with metal-metal unsupported bonds

Chem Commun (Camb). 2004 Aug 7:(15):1712-3. doi: 10.1039/b405532b. Epub 2004 Jun 28.

Authors

Inma Angurell¹, Isabel Martínez-Ruiz, Oriol Rossell, Miquel Seco, Pilar Gómez-Sal, Avelino Martin

Affiliation

¹ Departament de Quimica Inorganica, Universitat de Barcelona, Marti i Franques 1-11, E-08028 Barcelona, Spain.

PMID: 15278150
DOI: 10.1039/b405532b

Abstract

Tri(N-pyrrolyl)phosphine reacted with the sigma/pi complex [Pd(mu-Cl)(COD-MeO)]2 to give the octa-cycle [Pd(mu-Cl)[P(pyrl)3]]8 containing four Pd(I)-Pd(I) unbridged bonds.